资源化学领域

 

 

  简历: 

  2015/5-至今 中国科学院兰州化学物理研究所苏州研究院,研究员,博士生导师
    2015/3-至今 中国科学院兰州化学物理研究所,研究员,博士生导师
    2010/8-2015/3 美国得州大学西南医学中心,博士后,导师:Chuo Chen 教授
    2005/9-2010/7 中国科学院上海有机化学研究所,博士,导师:游书力 研究员
    2001/9-2005/7 山东师范大学,学士
 

  研究方向: 

 碳一(C1)分子和低碳烯烃转化,惰性化学键活化转化,羰基合成与催化转化 

  获奖及荣誉: 

  2020 Thieme Chemistry Journals Award 
    2015 中科院“人才计划”
 

  承担科研项目: 

  中科院“人才计划”项目 (择优支持) 2015/12-2018/11, 项目负责人
    国家自然科学基金面上项目 (21572238) 2016/01-2017/12, 项目负责人
    江苏自然科学基金面上项目 (BK20161260) 2016/7-2019/6, 项目负责人
    国家自然科学基金面上项目 (21772208) 2018/01-2021/12, 项目负责人
  

    代表论著: 

  28. Zhang, Z.-B.; Yang Y.; Yu, Z.-X.; Xia, J.-B. Lewis Base-Catalyzed Amino-Acylation of Arylallenes via C–N Bond Cleavage: Reaction Development and Mechanistic Studies. ACS Catal. 2020, 10, 5419-5429. [HTML]
        27. Li, Y.-L.; Li W.-D.; Gu, Z.-Y.; Chen, J.; Xia, J.-B. Photoredox Ni-catalyzed Branch-Selective Reductive Coupling of Aldehydes with 1,3-Dienes. ACS Catal. 2020, 10, 1528-1534. [HTML]
        26. Li, W.-D.; Zhu, D.-Y.; Li, G.; Chen, J.; Xia, J.-B. Iron-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2. Adv. Synth. Catal. 2019, 361, 5098-5104. [HTML] VIP Paper, Front Cover
        25. Yuan, S.-W.; Han, H.; Li, Y.-L.; Wu, X.; Bao, X.; Gu, Z.-Y.; Xia, J.-B. Intermolecular C–H Amidation of (Hetero)arenes to Produce Amides through Rhodium-Catalyzed Carbonylation of Nitrene Intermediate. Angew. Chem. Int. Ed. 2019, 58, 8887-8892. [HTML] 
       ·Highlighted in Chin. J. Org. Chem. 2019, 39, 2681.
       24. Han, H.; Fang, L.; Chen, J.; Yang, S.-D.; Xia, J.-B. Tetramethylguanidine (TMG)-Catalyzed Reductive Spirocyclization of Tryptamine Derivatives with Formic Acid as a C1 Synthon. Tetrahedron Lett. 2019, 60, 1487-1489. [HTML]
        23. Han, H.; Zhang, T.; Yang, S.-D.; Lan, Y.; Xia, J.-B. Palladium-Catalyzed Enantioselective C–H Aminocarbonylation: Synthesis of Chiral Isoquinolinones. Org. Lett. 2019, 21, 1749-1754. [HTML]
        22. Han, H.; Yang, S.-D.; Xia, J.-B. Pd/Cu Cocatalyzed Oxidative Tandem C–H Aminocarbonylation and Dehydrogenation of Tryptamines: Synthesis of Carbolinones. J. Org. Chem. 2019, 84, 3357-3369. [HTML]
        21. Zhang, Z.-B.; Ji, C.-L.; Yang, C.; Chen, J.; Hong, X.; Xia, J.-B. Nickel-Catalyzed Kumada Coupling of Boc-Activated Aromatic Amines via Nondirected Selective Aryl C?N Bond Cleavage. Org. Lett. 2019, 21, 1226-1231. [HTML] 
       ·Highlighted by P. Knochel and S. Graβl in Synfacts 2019, 15, 526.
        20. Li, G.; Chen, Y.; Xia, J.-B. Progress on Transition-Metal-Catalyzed Cross-coupling Reactions of Ammonium Salts via C–N Bond Cleavage. Chin. J. Org. Chem. 2018, 38, 1949-1962. [HTML]
        19. Li, G.; Chen, J.; Zhu, D.-Y.; Chen, Y.; Xia, J.-B. DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane. Adv. Synth. Catal. 2018, 360, 2364-2369. [HTML]
        18. Zhu, D.-Y.; Li, W.-D.; Yang, C.; Chen. J.; Xia, J.-B. Transition-Metal-Free Reductive Deoxygenative Olefination with CO2. Org. Lett. 2018, 20, 3282-3285. [HTML]
        17. Zhu, D.-Y.; Fang, L.; Han, H.; Wang Y.; Xia, J.-B. Reductive CO2 Fixation via Tandem C–C and C–N Bond Formation: Synthesis of Spiro-indolepyrrolidines. Org. Lett. 2017, 19, 4259-4262. [HTML]
        16. Zhu, D.-Y.; Chen, P.; Xia, J.-B. Synthesis of Planar Chiral Ferrocenes by Transition-Metal-Catalyzed Enantioselective C–H Activation. ChemCatChem, 2016, 8, 68-73. [HTML] 
        ·Publications from Graduate and Postdoctoral Studies:
        15. Han, L.; Xia, J.-B.; You, L.; Chen, C. Ketone-catalyzed photochemical C(sp3)–H chlorination. Tetrahedron 2017, 73, 3696-3701.
        14. Xia, J.-B.; Zhu, C.; Chen, C. Visible Light-Promoted Metal-Free sp3-C–H Fluorination Chem. Commun. 2014, 50, 11701-11704.
        13. Xia, J.-B.; Ma, Y.; Chen, C. Vanadium-Catalyzed C(sp3)–H Fluorination Reactions. Org. Chem. Front. 2014, 1, 468-472. 
        ·One of three hot articles in April, 2014. 
        ·One of top ten most-read articles from April to June, 2014.
        12. Zhu, C.; Xia, J.-B.; Chen, C. A Simple Method for the Electrophilic Cyanation of Secondary Amines. Org. Lett. 2014, 16, 247-250.
        11. Zhu, C.; Xia, J.-B.; Chen, C. Vanadium-Catalyzed Oxidative Strecker Reaction: α-C–H Cyanation of para-Methoxyphenyl (PMP)-Protected Primary Amines. Tetrahedron Lett. 2014, 55, 232-234.
        10. Xia, J.-B.; Zhu, C.; Chen, C. Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination. J. Am. Chem. Soc. 2013, 135, 17494-17500. 
         ·Highlighted in Synfacts 2014, 10, 85; Org. Chem. Front. 2014, 1, 434-438.
        9. Xia, J.-B.; Cormier, K. W.; Chen, C. A Highly Selective Vanadium Catalyst for Benzylic C–H Oxidation. Chem. Sci. 2012, 3, 2240-2245. 
         ·One of top ten most accessed articles in April, 2012.
        8. Liu, W.-B.; Xia, J.-B.; You, S.-L. Iridium-Catalyzed Asymmetric Allylic Substitutions Top. Organomet. Chem. 2012, 38, 155-208.
        7. Xia, J.-B.; Liu, W.-B.; Wang, T.-M.; You, S.-L. Enantioselective Synthesis of 3-Azabicyclo[4.1.0]heptanes and 3-Azabicyclo[3.2.0]heptanes via Ir-Catalyzed Asymmetric Allylic Amination of N-Tosyl Propynylamine and Pt-Catalyzed Cycloisomerization Reaction. Chem. Eur. J. 2010, 16, 6442-6446. 
       ·Highlighted in Synfacts 2010, 8, 909.
        6. Xia, J.-B.; Zhuo, C.-X.; You, S.-L. Synthesis of Cyclopropane-containing Building Blocks via Ir-Catalyzed Enantioselective Allylic Substitution Reaction. Chin. J. Chem. 2010, 28, 1525-1528. 
        ·Invited paper for celebrating the 60th Anniversary of SIOC.
        5. You, S.-L.; Xia, J.-B. Palladium-Catalyzed Aryl–Aryl Bond Formation through Double C–H Activation. Top. Curr. Chem. 2010, 292, 165-194.
        4. Xia, J.-B.; You, S.-L. Synthesis of 3-Haloindolizines by Copper(II) Halides Mediated Direct Functionalization of Indolizines. Org. Lett. 2009, 11, 1187-1190.
        3. Xia, J.-B.; Wang, X.-Q.; You, S.-L. Synthesis of Biindolizines through Highly Regioselective Palladium-Catalyzed C–H Functionalization. J. Org. Chem. 2009, 74, 456-458.
        2. Wang, X.-Q.; Xia, J.-B.; Dai, X.-Y.; You, S.-L. Preparation of Ferrocenyl Imidazolines using Bis(triphenyl)oxodiphosphonium Trifluoromethansulfonate. Sci. China Chem. 2009, 52, 1331-1336. 
        ·Invited paper for the 90th Anniversary of Nankai University.
        1. Xia, J.-B.; You, S.-L. Carbon–Carbon Bond Formation through Double sp2 C–H Activations: Synthesis of Ferrocenyl Oxazoline Derivatives. Organometallics 2007, 26, 4869-4871. 
        ·One of the most-accessed articles in July-September 2007.

        Book Chapters
        2. Xia, J.-B.; You, S.-L. C–C Bond Formation via Double C–H Bond Activation. in Science of Synthesis, Yu, J.-Q., Ed, Thieme: Stuttgart, 2015 115-136.
        1. Xia, J.-B.; Jamison, T. F.; You, S.-L. Monodentate Chiral Ferrocenyl Ligands. in Chiral Ferrocenes in Asymmetric Catalysis, Dai, L.-X., Hou, X.-L., Eds, WILEY-VCH: Weinheim, 2010, pp. 55-71.

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